Синтез, выращивание монокристаллов и электрофизические свойства соединений CuMBi3S6 и CuMEr3S6 (M–Pb, Ca, Eu, Yb)

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

Методами термического, рентгенофазового, микроструктурного анализов, измерением микротвердости и электрофизических свойств установлено образование соединений состава CuMBi3S6 и CuMEr3S6 (M – Eu, Pb, Yb, Ca). Показано, что полученные соединения изоструктурны, кристаллизуются в орторомбичесской сингонии (a = 11.201–11.236, b = 11.561–11.420, с = 4.003–3.966 Å, Z = 4, пр.гр. Pb21m, d = 4.17–3.570 г/см3) и относятся к структурному типу крупкаита CuPbBi3S6. Соединения типа CuMBi3S6 и CuMEr3S6 являются полупроводниками р-типа проводимости, вычислена их ширина запрещенной зоны.

Авторлар туралы

O. Aliyev

Institute of Catalysis and Inorganic Chemistry named after Academician M. Nagiev of the Ministry of Science and Education of the Republic of Azerbaijan

Email: iradam@rambler.ru
G. Javid Avenue, 113, Baku, Az 1143 Azerbaijan

D. Ajdarova

Institute of Catalysis and Inorganic Chemistry named after Academician M. Nagiev of the Ministry of Science and Education of the Republic of Azerbaijan

G. Javid Avenue, 113, Baku, Az 1143 Azerbaijan

V. Ragimova

Institute of Catalysis and Inorganic Chemistry named after Academician M. Nagiev of the Ministry of Science and Education of the Republic of Azerbaijan

G. Javid Avenue, 113, Baku, Az 1143 Azerbaijan

T. Maksudova

Institute of Catalysis and Inorganic Chemistry named after Academician M. Nagiev of the Ministry of Science and Education of the Republic of Azerbaijan

G. Javid Avenue, 113, Baku, Az 1143 Azerbaijan

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