Sorption of neutral red dye by entersorbent polysorb mp from aot microemulsion in N-decan

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Abstract

Sorption of the cationic neutral red dye by Polysorb MP from a microemulsion of 0.25 mol/l AOT in n-decane was carried out at different contents of the aqueous pseudophase. The maximum sorption capacity of the sorbent in the microemulsion exceeded the corresponding one in the aqueous phase by an order of magnitude and amounted to 55 mg/g. A sharp drop in the degree of extraction with an increase in the water content of the microemulsion from 1 to 8 volume percent and the reversibility of sorption processes were demonstrated. Anionic dyes were not extracted by Polysorb MP in the same systems. With increasing water content, the zeta potential of SiO2 particles decreased from 18 to 1 mV. Based on the obtained dependencies, a cation exchange mechanism of microemulsion sorption was proposed, including the exchange of sodium and neutral red cations between micelles adsorbed on the surface of particles and micelles in the bulk of the microemulsion.

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M. G. Demidova

Федеральное государственное бюджетное учреждение науки Институт неорганической химии им А.В. Николаева СО РАН

Email: nikshapar@mail.ru
Russian Federation, Новосибирск

T. Yu. Podlipskaya

Федеральное государственное бюджетное учреждение науки Институт неорганической химии им А.В. Николаева СО РАН

Email: nikshapar@mail.ru
Russian Federation, Новосибирск

N. O. Shaparenko

Федеральное государственное бюджетное учреждение науки Институт неорганической химии им А.В. Николаева СО РАН

Author for correspondence.
Email: nikshapar@mail.ru
Russian Federation, Новосибирск

M. K. Barakina

Федеральное государственное бюджетное учреждение науки Институт неорганической химии им А.В. Николаева СО РАН; Новосибирский государственный университет

Email: nikshapar@mail.ru
Russian Federation, Новосибирск; Новосибирск

V. V. Tatarchuk

Федеральное государственное бюджетное учреждение науки Институт неорганической химии им А.В. Николаева СО РАН

Email: nikshapar@mail.ru
Russian Federation, Новосибирск

A. I. Bulavchenko

Федеральное государственное бюджетное учреждение науки Институт неорганической химии им А.В. Николаева СО РАН

Email: nikshapar@mail.ru
Russian Federation, Новосибирск

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2. Fig. 1. Absorption spectra of NC in AOT microemulsion in n-decane depending on the concentration of NC (a), and calibration dependences for water (1) and microemulsion (2) (b). The water content in the microemulsion is 0.4 vol.%.

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3. Fig. 2. Absorption spectra of NC (0.005 mg/ml) in water and microemulsion at water contents of 0.8 and 8 vol.% (a) and the dependence of the shift λmax of the absorption spectrum of NC in the microemulsion relative to its aqueous solution on the water content in the microemulsion and the parameter W (b).

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4. Fig. 3. Dependence of the hydrodynamic diameter of AOT micelles and the zeta potential of Polysorb particles on the content of the aqueous pseudophase in the microemulsion.

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5. Fig. 4. TEM (a) and HRTEM (b) – photographs of Polysorb MP powder and the primary particle size distribution function (inset).

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6. Fig. 5. Sorption isotherms (a) and extraction degree (b) of NC from water (1) and microemulsions with an aqueous pseudophase content of 0.4 (2) and 1.5 vol. % (3). The inset in Fig. a shows dependence 1 in the region of low concentrations.

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7. Fig. 6. The degree of NC extraction depending on the water content in the AOT microemulsion in decane. The initial concentration of NC was 0.005 mg/ml.

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