Extraction of actinides and lanthanides from nitric acid solutions with diphosphine dioxides in the presence of an ionic liquid

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The e ect of 1-butyl-3-methylimidazolium bis[(tri uoromethyl)sulfonyl]imide ionic liquid on the extraction of lanthanides(III), U(VI), and Th(IV) from nitric acid solutions with 1,2-bis(diphenylphosphinyl)ethane I and 1,2-bis(diphenylphosphinyl)benzene II has been studied. The stoichiometry of the extractable complexes was determined. A solution of dioxide II in dichloroethane extracts metal ions much more e ciently than a solution of dioxide I. It has been established that, in the presence of an ionic liquid in the organic phase, the e ciency of extraction of metal ions from nitric acid solutions with solutions of dioxide I increases signi cantly, while that of dioxide II decreases. As a result, in the presence of an ionic liquid in the organic phase, dioxide II is signi cantly inferior to dioxide I in terms of the e ciency of extraction of Ln(III), U(VI), and Th(IV) from nitric acid solutions, which is associated with a much higher ability of dioxide II to extract HTf2N.

作者简介

A. Turanov

Osipyan Institute of Solid State Physics, Russian Academy of Sciences

V. Karandashev

Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences

O. Artyushin

Nesmeyanov Institut e of Organoelement Compounds, Russian Academy of Sciences

V. Brel

Nesmeyanov Institut e of Organoelement Compounds, Russian Academy of Sciences

Email: v_brel@mail.ru

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