Adsorption of Cr(VI) by Nanosized Rutile under the Action of UV Radiation

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Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

the properties of nanosized sorbents prepared by high-energy milling from microcrystalline powder of titanium dioxide of rutile modification have been studied. It was established that milling to an average crystallite size of ~30 nm and ultraviolet illumination significantly improved the sorption properties of rutile with respect to chromium compared with those of the starting material and the ability of Cr(VI) to be reduced to Cr(III) in its presence. The maximum removal of Cr(VI) from aqueous solutions with a concentration of 50 mg/L was achieved under UV illumination in an acetate buffer medium at pH 4–5 and a content of ground rutile of 16.7 g/L. A mechanism of adsorption was proposed.

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Авторлар туралы

N. Pechishcheva

Institute of Metallurgy, Ural Branch, Russian Academy of Sciences

Email: pechischeva@gmail.com
620016, Yekaterinburg, Russia

D. Ordinartsev

Institute of Metallurgy, Ural Branch, Russian Academy of Sciences

Email: pechischeva@gmail.com
620016, Yekaterinburg, Russia

A. Valeeva

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the First President of Russia B. N. Yeltsin

Email: pechischeva@gmail.com
620108, Yekaterinburg, Russia; 620002, Yekaterinburg, Russia

P. Zaitseva

Institute of Metallurgy, Ural Branch, Russian Academy of Sciences

Email: pechischeva@gmail.com
620016, Yekaterinburg, Russia

A. Korobitsyna

Institute of Metallurgy, Ural Branch, Russian Academy of Sciences

Email: pechischeva@gmail.com
620016, Yekaterinburg, Russia

A. Sushnikova

Institute of Metallurgy, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the First President of Russia B. N. Yeltsin

Email: pechischeva@gmail.com
620016, Yekaterinburg, Russia; 620002, Yekaterinburg, Russia

A. Kim

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Email: pechischeva@gmail.com
620016, Yekaterinburg, Russia

K. Shunyaev

Institute of Metallurgy, Ural Branch, Russian Academy of Sciences

Email: pechischeva@gmail.com
620016, Yekaterinburg, Russia

A. Rempel

Institute of Metallurgy, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the First President of Russia B. N. Yeltsin

Хат алмасуға жауапты Автор.
Email: pechischeva@gmail.com
620016, Yekaterinburg, Russia; 620002, Yekaterinburg, Russia

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© Н.В. Печищева, Д.П. Ординарцев, А.А. Валеева, П.В. Зайцева, А.Д. Коробицына, А.А. Сушникова, А.В. Ким, К.Ю. Шуняев, А.А. Ремпель, 2023