Studying the electrochemical behavior of a smooth gold electrode in a solution of bridged 1,2,4-trioxalane in acetonitrile

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

The behavior of a smooth gold electrode in the medium of bridged 1,2,4-trioxalane in acetonitrile is studied by cyclic voltammetry and gravimetry methods. It is found that during the cathodic process, the reduction of the peroxide bond in the bridged 1,2,4-trioxalane molecule takes place at the electrode surface followed by the formation of a diketone moiety. During anodic oxidation, the formation of colloidal gold particles is detected.

Толық мәтін

Рұқсат жабық

Авторлар туралы

M. Polyakov

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: SatPolyak@yandex.ru
Ресей, Moscow, 119991

M. Vedenyapina

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Email: SatPolyak@yandex.ru
Ресей, Moscow, 119991

A. Skundin

A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Email: SatPolyak@yandex.ru
Ресей, Moscow, 119071

I. Yaryomenko

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Email: SatPolyak@yandex.ru
Ресей, Moscow, 119991

P. Radulov

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Email: SatPolyak@yandex.ru
Ресей, Moscow, 119991

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Әрекет
1. JATS XML
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2. Scheme 1. Obtaining the substrate under study 3.

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3. Fig. 1. CBA 3 in the cathodic region at the Au electrode, ν = 100, 150, 200, 250, 250, 300, 350, 350, 400, 450, 500 mV/s.

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4. Fig. 2. Dependences of Ipc - ν0.5 for the first (a) and second (b) cathode peaks of CBA.

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5. Fig. 3. CBA 3 in the anodic region at the Au electrode, ν = 100, 150, 200, 250, 250, 300, 350, 350, 400, 450, 500 mV/s.

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6. Fig. 4. Dependence of Ip,a on ν0.5.

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7. Fig. 5. Mass change of the gold anode, at I = 5 mA, in MeCN solution, the concentration of compound 3 was 0.05 M.

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8. Scheme 2. Electrochemical corrosion of gold in the presence of compound 3 in acetonitrile medium.

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9. Scheme 3. Cathodic reduction reaction of compound 3.

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