Structural modifications of the platinum(II) isocyanide complexes changing their solid-state luminescence

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Resumo

Cyclometallated platinum(II) complexes with the general formula [Pt(Рpy)(CNR)2]X (HРpy = 2-phenylpyridine; R = iPr, tBu, Cy; X = BF4, OTf, PF6) containing various alkylisocyanide ligands and counterions are synthesized. The compounds are studied by elemental analysis, ESI HRMS, IR spectroscopy, and 1H, 13C{1H}, and 195Pt{1H} NMR spectroscopy. The structures of [Pt(Рpy)(CNiPr)2]BF4 and [Pt(Рpy)(CNtBu)2]BF4 are determined by XRD (CIF files CCDC nos. 2325595 and 2325527, respectively). The photophysical properties in the solution and in the solid state of the synthesized compounds are studied.

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Sobre autores

E. Antonova

St. Petersburg State University

Email: m.kinzhalov@spbu.ru
Rússia, St. Petersburg

M. Sandzhieva

St. Petersburg National Research University of Information Technologies, Mechanics, and Optics

Email: m.kinzhalov@spbu.ru
Rússia, St. Petersburg

M. Kinzhalov

St. Petersburg State University

Autor responsável pela correspondência
Email: m.kinzhalov@spbu.ru
Rússia, St. Petersburg

Bibliografia

  1. Li X., Xie Y., Li Z. // Chem Asian J. 2021. V. 16. № 19. P. 2817. https://doi.org/10.1002/asia.202100784
  2. Lee S., Han W.-S. // Inorg. Chem. Front. 2020. V. 7. № 12. P. 2396. https://doi.org/10.1039/D0QI00001A
  3. Zhang Q.-C., Xiao H., Zhang X. et al. // Chem. Soc. Rev. 2019. V. 378. № . P. 121. https://doi.org/10.1016/j.ccr.2018.01.017
  4. Katkova S.A., Kozina D.O., Kisel K.S. et al. // Dalton Trans. 2023. V. 52. № 14. P. 4595. https://doi.org/10.1039/d3dt00080j.
  5. Zhou X., Lee S., Xu Z. et al. // Chem. Rev. 2015. V. 115. № 15. P. 7944. https://doi.org/10.1021/cr500567r
  6. Eremina A.A., Kinzhalov M.A., Katlenok E.A. et al. // Inorg. Chem. 2020. V. 59. № 4. P. 2209. https://doi.org/10.1021/acs.inorgchem.9b02833
  7. Chan A.Y., Perry I.B., Bissonnette N.B. et al. // Chem. Rev. 2021. V. № . P. https://doi.org/10.1021/acs.chemrev.1c00383
  8. Li K., Chen Y., Wang J. et al. // Coord. Chem. Rev. 2021. V. 433. № . P. 213755. https://doi.org/10.1016/j.ccr.2020.213755
  9. To W.P., Wan Q.Y., Tong G.S.M. et al. // Trends Chem. 2020. V. 2. № 9. P. 796. https://doi.org/10.1016/j.trechm.2020.06.004
  10. Kinzhalov M.A., Grachova E.V., Luzyanin K.V. // Inorg. Chem. Front. 2022. V. 9. № . P. 417. https://doi.org/10.1039/D1QI01288F
  11. Lu B., Liu S., Yan D. // Chin. Chem. Lett. 2019. V. 30. № 11. P. 1908. https://doi.org/10.1016/j.cclet.2019.09.012
  12. Wang W., Zhang Y., Jin W.J. // Coord. Chem. Rev. 2020. V. 404. № . P. https://doi.org/10.1016/j.ccr.2019.213107
  13. Koshevoy I.O., Krause M., Klein A. // Coord. Chem. Rev. 2020. V. 405. № . P. https://doi.org/10.1016/j.ccr.2019.213094
  14. Yoshida M., Kato M. // Coord. Chem. Rev. 2018. V. 355. № . P. 101. https://doi.org/10.1016/j.ccr.2017.07.016
  15. Puttock E.V., Walden M.T., Williams J.A.G. // Coord. Chem. Rev. 2018. V. 367. № . P. 127. https://doi.org/10.1016/j.ccr.2018.04.003
  16. Ravotto L., Ceroni P. // Coord. Chem. Rev. 2017. V. 346. № . P. 62. https://doi.org/10.1016/j.ccr.2017.01.006
  17. Solomatina A.I., Galenko E.E., Kozina D.O. et al. // Chemistry. 2022. V. 28. № 64. P. e202202207. https://doi.org/10.1002/chem.202202207
  18. Sokolova E.V., Kinzhalov M.A., Smirnov A.S. et al. // ACS Omega. 2022. V. 7. № 38. P. 34454. https://doi.org/10.1021/acsomega.2c04110
  19. Saito D., Ogawa T., Yoshida M. et al. // Angew. Chem. Int. Ed. Engl. 2020. V. 59. № 42. P. 18723. https://doi.org/10.1002/anie.202008383
  20. Yoshida M., Kato M. // Coord. Chem. Rev. 2020. V. 408. № . P. https://doi.org/10.1016/j.ccr.2020.213194
  21. Chaaban M., Lee S., Vellore Winfred J.S.R. et al. // Small Struct. 2022. V. 3. № 9. P. 2200043. https://doi.org/10.1002/sstr.202200043
  22. Ogawa T., Sameera W.M.C., Saito D. et al. // Inorg. Chem. 2018. V. 57. № 22. P. 14086. https://doi.org/10.1021/acs.inorgchem.8b01654.
  23. Law A.S., Lee L.C., Lo K.K. et al. // J. Am. Chem.Soc. 2021. V. 143. № 14. P. 5396. https://doi.org/10.1021/jacs.0c13327
  24. Po C., Tam A.Y., Wong K.M. et al. // J. Am. Chem. Soc. 2011. V. 133. № 31. P. 12136. https://doi.org/10.1021/ja203920w
  25. Cave G.W.V., Fanizzi F.P., Deeth R.J. et al. // Organometallics. 2000. V. 19. № 7. P. 1355. https://doi.org/10.1021/om9910423
  26. Liu J., Leung C.H., Chow A.L. et al. // Chem Commun. 2011. V. 47. № 2. P. 719. https://doi.org/10.1039/c0cc03641b
  27. Dobrynin M.V., Sokolova E.V., Kinzhalov M.A. et al. // ACS Appl. Polym. Mater. 2021. V. 3. № 2. P. 857. https://doi.org/10.1021/acsapm.0c01190
  28. Hubschle C.B., Sheldrick G.M., Dittrich B. // J. Appl. Crystallogr. 2011. V. 44. № 6. P. 1281. https://doi.org/10.1107/S0021889811043202
  29. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Crystallogr. 2009. V. 42. № 2. P. 339.
  30. CrysAlisPro. Yarnton (Oxfordshire, England): Agilent Technologies Ltd., 2012.
  31. CrysAlisPro. Yarnton (Oxfordshire, England): Agilent Technologies Ltd., 2014.
  32. CrysAlisPro. Yarnton (Oxfordshire, England): Oxford Diffraction Ltd., 2009.
  33. Katkova S.A., Sokolova E.V., Kinzhalov M.A. // Russ. J. Gen. Chem.. 2023. V. 93. № 1. P. 43. https://doi.org/10.1134/S1070363223010073
  34. Forniés J., Fuertes S., Larraz C. et al. // Organometallics. 2012. V. 31. № 7. P. 2729. https://doi.org/10.1021/om201036z
  35. Kinzhalov M.A., Boyarskii V.P. // Russ. J. Gen. Chem. 2015. V. 85. № 10. P. 2313. https://doi.org/10.1134/s1070363215100175
  36. Pawlak T., Niedzielska D., Vícha J. et al. // J. Organometal. Chem. 2014. V. 759. № . P. 58. https://doi.org/10.1016/j.jorganchem.2014.02.016
  37. Katkova S.A., Mikherdov A.S., Sokolova E.V. et al. // J. Mol. Struct. 2022. V. 1253. № . P. 132230. https://doi.org/10.1016/j.molstruc.2021.132230
  38. Katkova S.A., Eliseev I.I., Mikherdov A.S. et al. // Russ. J. Gen. Chem. 2021. V. 91. № 3. P. 393. https://doi.org/10.1134/S1070363221030099
  39. Martínez-Junquera M., Lara R., Lalinde E. et al. // J. Mater. Chem. C. 2020. V. 8. № 21. P. 7221. https://doi.org/10.1039/D0TC01163K
  40. Martinez-Junquera M., Lalinde E., Moreno M.T. // Inorg. Chem. 2022. V. 61. № 28. P. 10898. https://doi.org/10.1021/acs.inorgchem.2c01400
  41. Shahsavari H.R., Babadi Aghakhanpour R., Hossein-Abadi M. et al. // New J. Chem. 2017. V. 41. № 24. P. 15347. https://doi.org/10.1039/c7nj03110f
  42. Bondi A. // J. Phys. Chem. 1964. V. 68. № 3. P. 441. https://doi.org/10.1021/j100785a001.
  43. Katkova S.A., Luzyanin K.V., Novikov A.S. et al. // New J. Chem. 2021. V. 45. № 6. P. 2948 https://doi.org/10.1039/D0NJ05457G.
  44. Martinez-Junquera M., Lalinde E., Moreno M.T. et al. // Dalton Trans. 2021. V. 50. № 13. P. 4539. https://doi.org/10.1039/d1dt00480h

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2. Scheme 1: Synthesis of isocyanide complexes I-VIII.

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3. Fig. 1. Structures of the organometallic cation of complexes I (a) and III (b) according to PCA data.

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4. Fig. 2. Non-covalent interactions between organometallic cations in complexes I (a) and III (b).

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5. Fig. 3. Normalized luminescence spectra of powders I-VIII at 298 K.

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