Synthesis of Nickel(II) complex with 2,6-dichlorophenyl-substituted pyridylpyrazole

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The mononuclear nickel(II) complex [L2Ni(CH3OH)]Cl (I) was synthesized by the interaction of new ligand 2-(2,6-dichlorophenyl)-5-(pyridin-2-yl)-2,4-dihydro-3H-pyrazol-3-one (L) with nickel(II) chloride. The solvate of complex I with methanol [L2Ni(CH3OH)]Cl·3CH3OH and the initial ligand L were characterized by X-ray diffraction analysis (CCDC № 2314989 (I), 2314988 (L)). It was observed that ligand L exists in the pyrazolone form based on 1H NMR data, whereas in complex I, it is found in the pyrazolol form according to X-ray diffraction data. Complex I is a unique example of a pyrazolol complex in which the oxygen atom does not engage in coordinating with the transition metal ion to create the coordination polymer.

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作者简介

I. Nikovskii

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: igornikovskiy@mail.ru
俄罗斯联邦, Moscow

E. Safiullina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: igornikovskiy@mail.ru
俄罗斯联邦, Moscow

Yu. Nelyubina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Moscow Institute of Physics and Technology

Email: igornikovskiy@mail.ru
俄罗斯联邦, Moscow; Dolgoprudny, Moscow Region

参考

  1. Khusnutdinova J.R., Milstein D. // Angew. Chem. Int. Ed. 2015. V. 54. P. 12236. https://doi.org/10.1002/anie.201503873
  2. Kumar A., Daw P., Milstein D. // Chem. Rev. 2021. V. 122. P. 385. https://doi.org/10.1021/acs.chemrev.1c00412
  3. Peris E., Crabtree R.H. // Chem. Soc. Rev. 2018. V. 47. P. 1959. https://doi.org/10.1039/C7CS00693D
  4. Wodrich M.D., Hu X. // Nat. Rev. Chem. 2017. V. 2. P. 0099. https://doi.org/10.1038/s41570-017-0099
  5. Gunanathan C., Milstein D. // Acc. Chem. Res. 2011 V. 44. P. 588. https://doi.org/10.1021/ar2000265
  6. Frey M. // ChemBioChem. 2002. V. 3. P. 153. https://doi.org/10.1002/1439-7633(20020301)3:2/ 3<153::AID-CBIC153>3.0.CO;2-B
  7. Varela-Álvarez A., Musaev D.G. // Chem. Sci. 2013. V. 4. P. 3758. https://doi.org/10.1039/C3SC51723C
  8. Thenarukandiyil R., Paenurk E., Wong A. et al. // Inorg. Chem. 2021. V. 60. P. 18296. https://doi.org/10.1021/acs.inorgchem.1c02925
  9. Lindner R., van den Bosch B., Lutz M. et al. // Organometallics. 2011. V. 30. P. 499. https://doi.org/10.1021/om100804k
  10. Ben-Ari E., Leitus G., Shimon L.J. et al. // J. Am. Chem. Soc. 2006. V. 128. P. 15390–15391. https://doi.org/10.1021/ja066411i
  11. Yang X., Hall M.B. // J. Am. Chem. Soc. 2010. V. 132. P. 120. https://doi.org/10.1021/ja9041065
  12. Scharf A., Goldberg I., Vigalok A. // J. Am. Chem. Soc. 2013. V. 135. P. 967. https://doi.org/10.1021/ja310782k
  13. Elsby M.R., Baker R.T. // Chem. Soc. Rev. 2020. V. 49. P. 8933. https://doi.org/10.1039/D0CS00509F
  14. Roussel R., DeGuerrero M.O., Spegt P. et al. // J. Heterocycl. 1982. V. 19. P. 785–796. https://doi.org/10.1002/jhet.5570190416
  15. Frank J., Katritzky A.R. // J. Chem. Soc., Perkin Trans. 2. 1976. P. 1428. https://doi.org/10.1039/P29760001428
  16. Moore C.M., Dahl E.W., Szymczak N.K. // Curr. Opin. Chem. Biol. 2015. V. 25. P. 9. https://doi.org/10.1016/j.cbpa.2014.11.021
  17. Al-Otaibi J.S. // SpringerPlus. 2015. V. 4. P. 1. https://doi.org/10.1186/s40064-015-1363-2
  18. Pietrzycki W.A., Sepioł J., Tomasik P. et al. // Bull. Soc. Chim. 1993. V. 102. P. 709. https://doi.org/10.1002/bscb.19931021105
  19. Langer R., Diskin-Posner Y., Leitus G. et al. // Angew. Chem. 2011. V. 123. P. 10122. https://doi.org/10.1002/anie.201104542
  20. Langer R., Leitus G., Ben-David Y. et al. // Angew. Chem. Int. Ed. 2011. V. 50. P. 2120. https://doi.org/10.1002/anie.201007406
  21. Srimani D., Ben-David Y., Milstein D. // Angew. Chem. Int. Ed. 2013. V. 52. https://doi.org/10.1002/ange.201300574
  22. Dupau P., Tran Do M.L., Gaillard S., Renaud J.-L. // Angew. Chem. Int. Ed. 2014 V. 53. P. 13004. https://doi.org/10.1002/anie.201407613
  23. Zell T., Milstein D. // Acc. Chem. Res. 2015. V. 48. P. 1979. https://doi.org/10.1021/acs.accounts.5b00027
  24. Polezhaev A.V., Chen C.H., Kinne A. et al. // Inorg. Chem. 2017. V. 56. P. 9505. https://doi.org/10.1021/acs.inorgchem.7b00785
  25. Kuwata S., Ikariya T. // Chem. Comm. 2014. V. 50. P. 14290. https://doi.org/10.1039/C4CC04457F
  26. Pavlov A.A., Aleshin D.Y., Nikovskiy I.A. et al. // Eur. J. Inorg. Chem. 2019. V. 2019. P. 2819. https://doi.org/10.1002/ejic.201900432
  27. Tasker S.Z., Standley E.A., Jamison T.F. // Nature. 2014. V. 509. P 299. https://doi.org/10.1038/nature13274
  28. Chen F., Di Y.Y., Zhang G. // J. Chem. Soc. Pak. 2023. V. 45. P. 19. https://doi.org/10.52568/001191/JCSP/45.01.2023
  29. Nikovskiy I., Polezhaev A., Novikov V. et al. // Chem. Eur. J. 2020. V. 26. P. 5629. https://doi.org/10.1002/chem.202000047
  30. Strunin D.D., Nikovskii I.A., Dan’shina A.A. et al. // Russ. J. Coord. Chem. 2024. V. 50. P. 384. https://doi.org/10.1134/S1070328424600645
  31. Sheldrick G.M. // Acta Crystallogr. A. 2008. V. 64. P. 112. https://doi.org/10.1107/S0108767307043930
  32. Dolomanov O.V., Bourhis L.J., Gildea, R.J. et al. // J. Appl. Crystallogr. 2009. V. 42. P. 339. https://doi.org/10.1107/S0021889808042726
  33. Demaison J., Császár A.G. // J. Mol. Struct. 2012. V. 1023. P. 7. https://doi.org/10.1016/j.molstruc.2012.01.030
  34. Constable E.C., Housecroft C.E. // Molecules. 2019. V. 24. P. 3951. https://doi.org/10.3390/molecules24213951
  35. Teratani T., Koizumi T.A., Yamamoto T. et al. // Inorg. Chem. Commun. 2011. V. 14. P. 836. https://doi.org/10.1016/j.inoche.2011.03.001
  36. Crabtree R.H. // New J. Chem. 2011. V. 35. P. 18. https://doi.org/10.1039/C0NJ00776E

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2. Rice. 1. 1H NMR spectrum of ligand L in CDCl3.

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3. Fig. 2. General view of the ligand L (a) and the hydrogen-bonded cycle (b) in the crystal of L CH3OH with atoms represented by thermal vibration ellipsoids (p = 50%). The dotted lines show the intermolecular hydrogen bond.

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4. Fig. 3. General view of the [L2Ni(CH3OH)]+ complex cation in the [L2Ni(CH3OH)]Cl 3СH3OH crystal with atoms represented by thermal vibration ellipsoids (p = 50%). Hydrogen atoms, except for those belonging to the OH groups of the ligand L and the coordinated methanol molecule, are not shown, as are the chloride anion in the outer coordination sphere and the solvate methanol molecules; numbering is given only for the metal ion and heteroatoms.

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5. Scheme 1

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6. Scheme 2

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7. Scheme 3

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8. Scheme 4

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9. Scheme 5

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