Synthesis and Luminescent Properties of the Carbonyl-Isonitrile Re(I) Complex Based on Menthol-Modified Phenanthroline

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅或者付费存取

详细

A carbonyl-isonitrile complex of [Re(CO)₃(L)(m-XylylNC)]OTf formulation (m-XylylNC – 2,6-dimethyl-phenyl isocyanide) was synthesized based on the 1,10-phenanthroline ligand (L) containing a menthol fragment (MtO–) in position 2. The Re(I) atom in the cationic part of this complex has a distorted octahedral environment formed by the N,N′-chelate ligand L, one isonitrile ligand, and three CO ligands. The resulting compound exhibits bright green phosphorescence at room temperature in both the solid state and solution, with quantum yields of 15% and 10%, respectively.

全文:

受限制的访问

作者简介

M. Davydova

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: chemisufarm@yandex.ru
俄罗斯联邦, Novosibirsk

A. Agafontsev

Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: chemisufarm@yandex.ru
俄罗斯联邦, Novosibirsk

V. Yudin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: chemisufarm@yandex.ru
俄罗斯联邦, Novosibirsk

M. Rakhmanova

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: chemisufarm@yandex.ru
俄罗斯联邦, Novosibirsk

A. Artem’ev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: chemisufarm@yandex.ru
俄罗斯联邦, Novosibirsk

参考

  1. Kirgan R.A., Sullivan B.P., Rillema D.P. // Photochemistry and photophysics of coordination compounds II / Eds. Balzani V., Campagna S. Berlin, Heidelberg: Springer Berlin Heidelberg, 2007. P. 45.
  2. Abramov P.A., Dmitriev A.A., Kholin K.V. et al. // Electrochim. Acta. 2018, V. 270. P. 526. https://doi.org/10.1016/j.electacta.2018.03.111
  3. Abramov P.A., Brylev K.A., Vorob’ev A.Y. et al. // Polyhedron. 2017. V. 137. P. 231. https://doi.org/10.1016/j.poly.2017.08.046
  4. Абрамов П.А. // Журн. структур. химии. 2021 V. 62. P. 1513. https://doi.org/10.26902/JSC_id79933 (Abramov P.A. // J. Struct. Chem. 2021. V. 62. P. 1416. https://doi.org/10.1134/S0022476621090109).
  5. Abramov P.A., Gritsan N.P., Suturina E. A. et al. // Inorg. Chem. 2015. V. 54. P. 6727. https://doi.org/10.1021/acs.inorgchem.5b00407
  6. Nayeri S., Jamali S., Pavlovskiy V.V. et al. // Eur. J. Inorg. Chem. 2019. V. 2019. P. 4350. https://doi.org/10.1002/ejic.201900617
  7. Shakirova J.R., Nayeri S., Jamali S. et al. // ChemPlusChem. 2020. V. 85. P. 2518. https://doi.org/10.1002/cplu.202000597
  8. Kisel K.S., Baigildin V.A., Solomatina A.I. et al. // Molecules. 2023. V. 28. P. 348. https://doi.org/10.3390/molecules28010348
  9. Kisel K.S., Shakirova J.R., Pavlovskiy V.V. et al. // Inorg. Chem. 2023. V. 62. P. 18625. https://doi.org/10.1021/acs.inorgchem.3c02915
  10. Kisel K.S., Eskelinen T., Zafar W. et al. // Inorg. Chem. 2018. V. 57. P. 6349. https://doi.org/10.1021/acs.inorgchem.8b00422
  11. Kalyanasundaram K. // Faraday Trans. 2. 1986. V. 82. P. 2401. https://doi.org/10.1039/F29868202401
  12. Yu T., Tsang D.P.-K., Au V. K.-M. et al. // Chem. Eur. J. 2013. V. 19. P. 13418. https://doi.org/10.1002/chem.201301841
  13. Sacksteder L., Lee M., Demas J. et al. // J. Am. Chem. Soc. 1993. V. 115. P. 8230. https://doi.org/10.1021/ja00071a036
  14. Villegas J.M., Stoyanov S.R., Huang W. et al. // Inorg. Chem. 2005 V. 44. P. 2297. https://doi.org/10.1021/ic048786f
  15. Favale J.M., Jr., Danilov E.O., Yarnell J E. et al. // Inorg. Chem. 2019 V. 58. P. 8750. https://doi.org/10.1021/acs.inorgchem.9b01155
  16. Klemens T., Świtlicka A., Szlapa-Kula A. et al. // Organometallics. 2019. V. 38. P. 4206. https://doi.org/10.1021/acs.organomet.9b00517
  17. Taydakov I.V., Vashchenko A.A., Lyssenko K.A. et al. // ARKIVOC. 2017. V. 2017, P. 205. https://doi.org/10.24820/ark.5550190.p010.130
  18. Hostachy S., Policar C., Delsuc N. // Coord. Chem. Rev. 2017. V. 351. P. 172. https://doi.org/10.1016/j.ccr.2017.05.004
  19. Chelushkin P.S., Shakirova J.R., Kritchenkov I.S. et al. // Dalton Trans. 2022 V. 51. P. 1257. https://doi.org/10.1039/D1DT03077A
  20. Leonidova A., Gasser G. // ACS Chem. Biol. 2014. V.9. P. 2180. https://doi.org/10.1021/cb500528c
  21. Lee L.C.-C., Leung K.-K., Lo K.K.-W. // Dalton Trans. 2017. V. 46. P. 16357. https://doi.org/10.1039/C7DT03465B
  22. Kuninobu Y., Takai K. // Chem. Rev. 2011. V. 111. P. 1938. https://doi.org/10.1021/cr100241u
  23. Kisel K.S., Samandarsangari M., Sokolov V.V. et al. // Opt. Mater. 2025. V. 159. P. 116589. https://doi.org/10.1016/j.optmat.2024.116589
  24. Saleh N., Srebro M., Reynaldo T. et al. // Chem. Commun. 2015. V. 51. P. 3754. https://doi.org/10.1039/C5CC00453E
  25. Gauthier E.S., Abella L., Hellou N. et al. // Angew. Chem. Int. Ed. 2020. V. 59 P. 8394. https://doi.org/10.1002/anie.202002387
  26. Saleh N., Kundu D., Vanthuyne N. et al. // ChemPlusChem. 2020, Vol. 85, P. 2446. https://doi.org/10.1002/cplu.202000559
  27. Gauthier E.S., Abella L., Caytan E. et al. // Chem. Eur. J. 2023, Vol. 29, P. e202203477. https://doi.org/10.1002/chem.202203477
  28. Giuso V., Gourlaouen C., Delporte-Pébay M. et al. // Phys. Chem. Chem. Phys. 2024. V. 26. P. 4855. https://doi.org/10.1039/D3CP04300B
  29. Kundu D., Jelonek D., Del Rio N. et al. // Chem. Asian J. год ? V. n/a. Аrt. e202401735. https://doi.org/10.1002/asia.202401735
  30. Davydova M.P., Xu T., Agafontsev A.M. et al. // Angew. Chem. Int. Ed. 2025. V. 64. Аrt. e202419788. https://doi.org/10.1002/anie.202419788
  31. Bruker Apex3 Software Suite: Apex3, SADABS‐2016/2 and SAINT 8.40a. 2017. V. ? Bruker AXS Inc., Madison, WI, USA.
  32. Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053273314026370
  33. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053229614024218
  34. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Crystallogr. 2009. V. 42, P. 339. https://doi.org/10.1107/S0021889808042726
  35. van der Sluis P., Spek A.L. // Acta Crystallogr. A. 1990. V. 46. P. 194. https://doi.org/10.1107/S0108767389011189
  36. Ortega J.V., Khin K., van der Veer W.E. et al. // Inorg. Chem. 2000. V. 39. P. 3038. https://doi.org/10.1021/ic0006910
  37. Aechter B., Knizek J., Nöth H. et al. // Z. Kristallogr. NCS. 2005. V. 220. P. 107. https://doi.org/10.1524/ncrs.2005.220.14.107
  38. King A.P., Marker S.C., Swanda R.V. et al. // Chem. Eur. J. 2019. V. 25. P. 9206. https://doi.org/10.1002/chem.201902223
  39. Ko C.-C., Ng C.-O., Yiu S.-M. // Organometallics. 2012. V. 31. P. 7074. https://doi.org/10.1021/om300526e
  40. Marker S.C., King A.P., Granja S. et al. // Inorg. Chem. 2020. V. 59. P. 10285. https://doi.org/10.1021/acs.inorgchem.0c01442
  41. Тюпина М.Ю., Мирославов А.Е., Сидоренко Г.В. и др. // Журн. общ. химии. 2022. V. 92. P. 110. https://doi.org/10.31857/S0044460X22010127 (Tyupina M.Y., Miroslavov A.E., Sidorenko G.V. et al. // Russ. J. Gen. Chem. 2022, V. 92. P. 69. https://doi.org/10.1134/S1070363222010108).

补充文件

附件文件
动作
1. JATS XML
下载
2. Additional materials
下载 (293KB)
索引源数据
3. Scheme 1. Synthesis of complex I.

下载 (165KB)
索引源数据
4. Fig. 1. Structure of complex I. The disordered part of the menthol fragment and solvate molecules are not shown.

下载 (223KB)
索引源数据
5. Fig. 2. Channels in the structure of complex I along the direction [0 1 −1].

下载 (942KB)
索引源数据
6. Fig. 3. Powder and solution of complex I in daylight and UV light (365 nm) (a); normalized excitation (λem = 510 nm) and PL (λexc = 340 nm) spectra for a solid sample of I (b); normalized absorption, excitation (λem = 525 nm), and PL (λexc = 405 nm) spectra for a solution of I (MeCN, 10⁻⁵ mol/L) (c).

下载 (356KB)
索引源数据

版权所有 © Российская академия наук, 2025