Synthesis of 2-(3,5-diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)ethyl-ureas and -carbamates

The interaction of 1-(2-aminoethyl)-3,5-diallyl-2,4,6-trioxo-1,3,5-triazinan with phenylisocyanate and 1,6-hexamethylene diisocyanate gave new 3,5-diallyl-and 3,3',5,5'-tetraallylsubstituted isocyanurates containing one and two carbamide groups in their composition. The reaction of 1-(2-hydroxyethyl)-3,5-diallyl-2,4,6-trioxo-1,3,5-triazinan with phenyl isocyanate synthesized 1,3,5-triazinan-1-yl)ethyl-N-phenylcarbamate, and by alkylation of the sodium salt of 3,5-diallyl-2,4,6-trioxo-1,3,5-triazine bis(2-chloroethyl)hexane -1,6-diyldicarbamate was used to prepare bis-[2-(3,5-diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)ethyl]hexane-1,6-diyldicarbamate. The physical and spectral properties of the obtained 3,5-di- and 3,3',5,5'-tetraallyl isocyanurates were studied.

3,5-diallylisocyanurates, 3,3',5,5'-tetraallylisocyanurates, ureas, urethanes, mass spectrometry, IR and 1H NMR spectroscopy