Carbonylation and Other Transformations of Polyfluorobenzocyclobutenols in Super Acids

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Acid-catalyzed carbonylation of a number of polyfluorinated benzocyclobuten-1-ols, as well as cyclic sulfoesters of benzocyclobuten-1,2-diols, in reaction with carbon monoxide has been carried out. The efficiency of using TfOH and FSO3H-SbF5 as acidic systems was evaluated. Both products of CO addition with the remaining four-membered ring — the corresponding carboxylic acids, and various products of carbonylation accompanied by its transformations (ring opening, opening followed by heterocyclization with the formation of isochromane derivatives, expansion to a five-membered one) were obtained. In some cases, the formation of polycyclic dimeric products was also observed.

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作者简介

S. Wang

Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

编辑信件的主要联系方式.
Email: yzonov@nioch.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk

Ya. Zonov

Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: zonov@nioch.nsc.ru
ORCID iD: 0000-0003-0267-4976
俄罗斯联邦, Novosibirsk; Novosibirsk

V. Karpov

Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: zonov@nioch.nsc.ru
俄罗斯联邦, Novosibirsk

T. Mezhenkova

Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: zonov@nioch.nsc.ru
ORCID iD: 0000-0001-9936-0900
俄罗斯联邦, Novosibirsk

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